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'[EE] New form of Hydrogen storage for fuel cells.'
2006\09\14@092447
by
Russell McMahon
|
The following was triggered by a New Scientist articele about a "new"
way of storing Hydrogen for fuel calls. Google reveals it is far from
new, but worth knowing about.
The Stanford intro is superb:
http://gcep.stanford.edu/pdfs/hydrogen_workshop/Wu.pdf#search=%22borohydride%22
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Fuel cell which looks likely to allow practical devices with energy
desnities 3+ times higher than Lithium polymer cells. [[Also ISTM that
a specialist version of this with processing in use (dissolving solids
etc) could produce a system with energy densities several timeshigher
again.
The key factor is H2 storage as a borohydride and release using a
Ruthenium catalyst.
http://www.newscientisttech.com/article.ns?id=dn10066&print=true
No mention was made of any possible use for Hydrogen storage for
combustion (or propellants :-) ). Volumetric Hydrogen density may well
be high compared with LH but mass wise it's abysmal.
The mines at Boron may yet prove to have been fortuitously located.
___
Wikipedia well informed thereon
http://en.wikipedia.org/wiki/Sodium_borohydride
Stanford - very nice 22 page slideshow.
30% BH soln 63g H2/litre
LH 71g/l
5000 psi GH 23g/l
10,000 psi "G"H 39 g/l
http://gcep.stanford.edu/pdfs/hydrogen_workshop/Wu.pdf#search=%22borohydride%22
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Chemist Don Gervasio and colleague Sonja Tasic, both at Arizona State
University in the US, set out to develop a fuel cell that would
generate more electricity for its weight than the best batteries, and
would also work at room temperature.
Gervasio's solution was to use the alkaline compound borohydride. A
30% solution of borohydride in water actually contains one-third more
hydrogen than the same volume of liquid hydrogen.
"The difference is that the borohydride is at room temperature, and
it's stable, non-toxic and cost-effective," Gervasio says.
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